Poly[bis­(1H-imidazole)(μ3-7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)cadmium(II)]

نویسندگان

  • Na Wang
  • Yan-Jun Wang
  • Qiu-Yue Lin
چکیده

The title compound, [Cd(C(8)H(8)O(5))(C(3)H(4)N(2))(2)](n), was synthesized by the reaction of 7-oxabicyclo-[2.2.1]heptane-2,3-dicarboxylic anhydride, cadmium acetate and imidazole. The Cd(II) atom is seven-coordinated in a distorted penta-gonal-bipyramidal configuration by five O atoms from carboxyl-ate groups of three 7-oxabicyclo-[2.2.1]heptane-2,3-dicarboxylate ligands and two N atoms from two imidazole ligands. The crystal structure is stabilized by N-H⋯O and C-H⋯O hydrogen-bonding and C-H⋯π inter-actions.

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عنوان ژورنال:

دوره 65  شماره 

صفحات  -

تاریخ انتشار 2009